بررسی اثر تابش پلاسمایی نانوساختارهای کربن شبه الماس بر عملکرد جداسازی غشاهایی بر پایه PES، PP و PVDF

نویسندگان

1 دانشگاه تفرش

2 دانشگاه شهید بهشتی

چکیده
چالش رو به رشد رسوب غشایی در فرآیندهای تصفیه آب، به ویژه در کارخانه های نمک زدایی، نیازمند رویکردهای نوآورانه برای افزایش عملکرد غشا است. این مطالعه یک استراتژی جدید اصلاح سطح را برای غشاهای متفاوت (PES, PVDF, PP) با استفاده از نانوساختارهای کربن شبه الماس از طریق رسوب دهی بخار شیمیایی افزایش‌یافته با پلاسما ارائه می‌کند. اهداف اولیه بهبود آبدوستی غشا، افزایش خواص ضدرسوب و افزایش راندمان دفع نمک با حفظ یکپارچگی ساختاری بود. یک بررسی سیستماتیک برای مقایسه اصلاحات پوشش نانوساختارهای کربن شبه الماس تحت شرایط بهینه پلاسما (قدرت 40 وات، فشار 70 میلی‌تور، تابشدهی 30 دقیقه‌ای) انجام شد. مشخصه‌های سطحی هر سه غشای مورد مطالعه، ترکیب موفقیت‌آمیز نانوساختارهای کربن شبه الماس را نشان داد، که توسط طیف‌سنجی FTIR تأیید شد و تجزیه و تحلیل رامان که پوشش کربنی یکنواخت را بدون تشکیل ساختار کریستالی نشان می‌دهد. غشاهای اصلاح شده بهبود قابل توجهی در خواص سطحی نشان دادند، که نشان دهنده افزایش آبدوستی است. تجزیه و تحلیل AFM صاف شدن سطح قابل توجهی را نشان داد، که به بهبود خواص ضد رسوب کمک می کند. ارزیابی عملکرد پیشرفت‌های استثنایی را در پارامترهای کلیدی غشاهای PES, PVDF نشان داد: شار آب خالص افزایش یافت، در حالی که دفع نمک تا 99٪ بهبود یافت. غشاهای اصلاح‌شده به نرخ بازیابی شار بالایی در مقایسه با غشای اصلاح ‌نشده دست یافت که نشان‌دهنده خواص ضد رسوب برتر است. تست های پایداری در محلول های نمک اشباع، خواص تمیز کنندگی آسان و حفظ آبدوستی را پس از چندین دوره شستشو نشان داد که نشان دهنده دوام عالی است. این کار یک رویکرد اقتصادی مقرون به صرفه را برای توسعه غشاهای ضد رسوب با کارایی بالا با کاربردهای بالقوه در کارخانه‌های نمک‌زدایی و تأسیسات تصفیه فاضلاب معرفی می‌کند. یافته‌ها بینش‌های ارزشمندی را در مورد رابطه بین اصلاح سطح، ویژگی‌های ساختاری و عملکرد غشاء ارائه می‌دهند و به پیشرفت فناوری‌های تصفیه آب پایدار کمک می‌کنند.

کلیدواژه‌ها


عنوان مقاله English

Investigating the effect of plasma irradiation of diamond-like carbon nanostructures on the separation performance of membranes based on PES, PP and PVDF

نویسندگان English

Zeynab Kiamehr 1
Mojtaba Shafiee 2
Babak Shokri 2
Seyed Ali Razavi Rad 2
1 Tafresh University
2 Shahid Beheshti University
چکیده English

The growing challenge of membrane fouling in water treatment processes, especially in desalination plants, requires innovative approaches to enhance membrane performance. This study presents a novel surface modification strategy for different membranes (PES, PVDF, PP) using diamond-like carbon nanostructures via plasma-enhanced chemical vapor deposition. The primary objectives were to improve membrane hydrophilicity, enhance antifouling properties, and increase salt rejection efficiency while maintaining structural integrity. A systematic review compared diamond-like carbon nanostructure coating modifications under optimized plasma conditions (40 W power, 70 mTorr pressure, 30 min irradiation). The surface characterization of all three studied membranes demonstrated the successful incorporation of diamond-like carbon nanostructures, as confirmed by FTIR spectroscopy and Raman analysis, which revealed a uniform carbon coating without forming a crystalline structure. The modified membranes showed significant improvement in surface properties, indicating increased hydrophilicity. AFM analysis revealed significant surface smoothing, which contributes to improved antifouling properties. Performance evaluation revealed exceptional improvements in key parameters of PES, and PVDF membranes: pure water flux increased, while salt rejection improved by up to 99%. The modified membranes achieved high flux recovery rates compared to the unmodified membrane, indicating superior antifouling properties. Stability tests in saturated salt solutions revealed easy cleaning properties and hydrophilicity retention after multiple wash cycles, indicating excellent durability. This work introduces a cost-effective approach to developing high-performance antifouling membranes with potential applications in desalination plants and wastewater treatment facilities. The findings provide valuable insights into the relationship between surface modification, structural properties, and membrane performance, and contribute to the advancement of sustainable water treatment technologies.

کلیدواژه‌ها English

Surface modification
plasma modification
high permeability membrane
diamond-like carbon nanostructures
antifouling
desalination
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