تولید فرآورده گازی بر اساس پالایش نفت سنگین با استفاده از پلاسمای غیرحرارتی

نویسندگان

دانشگاه خوارزمی

چکیده


چکیده

تولید فرآورده‌های گازی از طریق فناوری پلاسمای غیرحرارتی روشی نوین برای پالایش نفت سنگین یا پسماندهای نفتی است. در این مطالعه، از پلاسمای جرقه در حباب گاز برای شکستن پیوندهای هیدروکربنی موجود در نفت و تولید محصولات گازی ارزشمند استفاده شد. به‌طورکلی، هدف این تحقیق توسعه روش کارآمدتر و پایدارتر برای پالایش نفت سنگین یا باقیمانده‌های ستون تقطیر با استفاده از پلاسمای غیرحرارتی است. در این مطالعه شرح ساخت راکتور طراحی شده در پژوهشگاه پلاسمای دانشگاه خوارزمی، مراحل و مدار ایجاد پلاسمای جرقه، روش جمع‌آوری گاز و روش سنجش فراورده‌های گازی بررسی می‌شود. در راکتور نفت سنگین ریخته شد و از گاز آرگون برای پاک‌کردن مدار از اکسیژن استفاده شد. بعلاوه در حباب‌های گاز آرگون که درون مایع نفتی دمیده شدند جرقه‌های پلاسما ایجاد شد. در مقاله به بررسی نحوه بکار گیری و بهینه‌سازی استفاده از گاز پرداخته می‌شود. فرآورده‌های گازی به دست آمده‌ای که بیشترین درصد مخلوط گازی را تشکیل می‌دهند؛ هگزان (13.8درصد)، پنتان (15.7درصد)، 2-متیل بوتان (12.75درصد)هستند.پس از اعمال پلاسما و ذخیره‌سازی فرآورده گازی، نفت سنگین باقی مانده دچار تغییر حالت محسوس نگشته و همچنان برای مصارف قبل قابل بهره برداری است.

کلیدواژه‌ها


عنوان مقاله English

generating gaseous products based on heavy oil refining by using non-thermal plasma

نویسندگان English

kamal Hajisharifi
Fatemeh shirkavand
Hasan Mahdian
Mahdi Bakhshzad Mahmoodi
Kharazmi University
چکیده English

Production of gaseous products through non-thermal plasma technology is an innovative method for refining heavy oil or petroleum residues. In this study, plasma sparks were generated in gas bubbles to break the hydrocarbon bonds in oil and produce valuable gaseous products. This research aims to develop a more efficient and sustainable method for refining heavy oil or distillation column residues using non-thermal plasma. This study describes the construction of a reactor designed at the Plasma Research Institute of Kharazmi University, the stages and circuitry for generating plasma sparks, the method of gas collection, and the analysis techniques for gaseous products. Heavy oil was poured into the reactor, and argon gas was used to purge the circuit of oxygen. Additionally, plasma sparks were generated in argon gas bubbles injected into the oil. The paper examines the utilization and optimization of gas usage in the process. The primary gaseous products obtained, forming the highest percentage of the gas mixture, were hexane (13.8%) , pentane (15.7%) , and 2-methylbutane (12.75%). After plasma application and gaseous product storage, the remaining heavy oil exhibited no significant changes in its state and remained suitable for its original uses.


کلیدواژه‌ها English

heavy oil
Gasification
non-thermal plasma
[1] S. M. Slavens, "Microplasma Ball Reactor for Liquid Hydrocarbon Conversion," 2014.
[1] S. M. Slavens, "Microplasma Ball Reactor for Liquid Hydrocarbon Conversion," 2014.
[2] R. Ganapathi, A. Henni, and E. Shirif, "Solubility of carbon dioxide and ethane in Lloydminster heavy oil: Experimental study and modelling," The Canadian Journal of Chemical Engineering, vol. 100, no. 6, pp. 1235-1243, 2022. [DOI:10.1002/cjce.24327]
[2] R. Ganapathi, A. Henni, and E. Shirif, "Solubility of carbon dioxide and ethane in Lloydminster heavy oil: Experimental study and modelling," The Canadian Journal of Chemical Engineering, vol. 100, no. 6, pp. 1235-1243, 2022. [DOI:10.1002/cjce.24327]
[3] R. Santos, W. Loh, A. Bannwart, and O. Trevisan, "An overview of heavy oil properties and its recovery and transportation methods," Brazilian Journal of Chemical Engineering, vol. 31, pp571-590., 2014. [DOI:10.1590/0104-6632.20140313s00001853]
[3] R. Santos, W. Loh, A. Bannwart, and O. Trevisan, "An overview of heavy oil properties and its recovery and transportation methods," Brazilian Journal of Chemical Engineering, vol. 31, pp571-590., 2014. [DOI:10.1590/0104-6632.20140313s00001853]
[4] S. Houda, C. Lancelot, P. Blanchard, L. Poinel, and C. Lamonier, "Oxidative desulfurization of heavy oils with high sulfur content: A review," Catalysts, vol. 8, no. 9, p. 344, 2018. [DOI:10.3390/catal8090344]
[4] S. Houda, C. Lancelot, P. Blanchard, L. Poinel, and C. Lamonier, "Oxidative desulfurization of heavy oils with high sulfur content: A review," Catalysts, vol. 8, no. 9, p. 344, 2018. [DOI:10.3390/catal8090344]
[5] M. Al-Samhan, J. Al-Fadhli, A. M. Al-Otaibi, F. Al-Attar, R. Bouresli, and M. S. Rana, "Prospects of refinery switching from conventional to integrated: An opportunity for sustainable investment in the petrochemical industry," Fuel, vol. 310, p. 122161, 2022. [DOI:10.1016/j.fuel.2021.122161]
[5] M. Al-Samhan, J. Al-Fadhli, A. M. Al-Otaibi, F. Al-Attar, R. Bouresli, and M. S. Rana, "Prospects of refinery switching from conventional to integrated: An opportunity for sustainable investment in the petrochemical industry," Fuel, vol. 310, p. 122161, 2022. [DOI:10.1016/j.fuel.2021.122161]
[6] J. D. Ampah et al., "Study on characteristics of marine heavy fuel oil and low carbon alcohol blended fuels at different temperatures," Fuel, vol. 310, p. 122307, 2022. [DOI:10.1016/j.fuel.2021.122307]
[6] J. D. Ampah et al., "Study on characteristics of marine heavy fuel oil and low carbon alcohol blended fuels at different temperatures," Fuel, vol. 310, p. 122307, 2022. [DOI:10.1016/j.fuel.2021.122307]
[7] N. Gao, J. Li, C. Quan, and H. Tan, "Product property and environmental risk assessment of heavy metals during pyrolysis of oily sludge with fly ash additive," Fuel, vol. 266, p. 117090, 2020. [DOI:10.1016/j.fuel.2020.117090]
[7] N. Gao, J. Li, C. Quan, and H. Tan, "Product property and environmental risk assessment of heavy metals during pyrolysis of oily sludge with fly ash additive," Fuel, vol. 266, p. 117090, 2020. [DOI:10.1016/j.fuel.2020.117090]
[8] S. S. Bello et al., "A review on the reaction mechanism of hydrodesulfurization and hydrodenitrogenation in heavy oil upgrading," Energy & Fuels, vol. 35, no. 14, pp 10998-11016. 2021 [DOI:10.1021/acs.energyfuels.1c01015]
[8] S. S. Bello et al., "A review on the reaction mechanism of hydrodesulfurization and hydrodenitrogenation in heavy oil upgrading," Energy & Fuels, vol. 35, no. 14, pp 10998-11016. 2021 [DOI:10.1021/acs.energyfuels.1c01015]
[9] R. Prajapati, K. Kohli, and S. K. Maity, "Slurry phase hydrocracking of heavy oil and residue to produce lighter fuels: An experimental review," Fuel, vol. 288, p. 119686, 2021. [DOI:10.1016/j.fuel.2020.119686]
[9] R. Prajapati, K. Kohli, and S. K. Maity, "Slurry phase hydrocracking of heavy oil and residue to produce lighter fuels: An experimental review," Fuel, vol. 288, p. 119686, 2021. [DOI:10.1016/j.fuel.2020.119686]
[10] H. M. Nguyen, A. Omidkar, W. Li, Z. Li, and H. Song, "Non-thermal plasma catalysis driven sustainable pyrolysis oil upgrading to jet fuel under near-ambient conditions," EES Catalysis, vol. 2, no. 2, pp. 647-663, 2024. [DOI:10.1039/D3EY00309D]
[10] H. M. Nguyen, A. Omidkar, W. Li, Z. Li, and H. Song, "Non-thermal plasma catalysis driven sustainable pyrolysis oil upgrading to jet fuel under near-ambient conditions," EES Catalysis, vol. 2, no. 2, pp. 647-663, 2024. [DOI:10.1039/D3EY00309D]
[11] H. Hao, P. Lian, J. Gong, and R. Gao, "Theoretical study on the hydrogenation mechanisms of model compounds of heavy oil in a plasma-driven catalytic system," Catalysts, vol. 8, no. 9, p. 381, 2018. [DOI:10.3390/catal8090381]
[11] H. Hao, P. Lian, J. Gong, and R. Gao, "Theoretical study on the hydrogenation mechanisms of model compounds of heavy oil in a plasma-driven catalytic system," Catalysts, vol. 8, no. 9, p. 381, 2018. [DOI:10.3390/catal8090381]
[12] P. J. Bruggeman et al., "Plasma-liquid interactions: a review and roadmap," Plasma sources science and technology, vol. 25, no. 5, p. 053002, 2016.
[12] P. J. Bruggeman et al., "Plasma-liquid interactions: a review and roadmap," Plasma sources science and technology, vol. 25, no. 5, p. 053002, 2016.
[13] A. D'Angola, G. Colonna, and E. Kustova, "Thermal and non-thermal plasmas at atmospheric pressure," vol. 10, ed: Frontiers Media SA, p. 852905., 2022. [DOI:10.3389/fphy.2022.852905]
[13] A. D'Angola, G. Colonna, and E. Kustova, "Thermal and non-thermal plasmas at atmospheric pressure," vol. 10, ed: Frontiers Media SA, p. 852905., 2022. [DOI:10.3389/fphy.2022.852905]
[14] J. Amouroux and M. Nikravech, "Process for the hydrocracking of a hydrocarbon feedstock and hydrocracking plant for carrying," ed: Google Patents, 1990.
[14] J. Amouroux and M. Nikravech, "Process for the hydrocracking of a hydrocarbon feedstock and hydrocracking plant for carrying," ed: Google Patents, 1990.
[15] H. Gil, "Method of upgrading bitumen and heavy oil," ed: Google Patents, 2009.
[15] H. Gil, "Method of upgrading bitumen and heavy oil," ed: Google Patents, 2009.
[16] Y. Matsui, S. Kawakami, K. Takashima, S. Katsura, and A. Mizuno, "Liquid-phase fuel re-forming at room temperature using nonthermal plasma," Energy & fuels, vol. 19, no. 4, pp. 1561-1565, 2005. [DOI:10.1021/ef0497816]
[16] Y. Matsui, S. Kawakami, K. Takashima, S. Katsura, and A. Mizuno, "Liquid-phase fuel re-forming at room temperature using nonthermal plasma," Energy & fuels, vol. 19, no. 4, pp. 1561-1565, 2005. [DOI:10.1021/ef0497816]
[17] J. Norem, Z. Insepov, and A. Hassanein, "An integrated approach to understanding RF vacuum arcs," Scientific Reports, vol. 11, no. 1, p. 2361, 2021. [DOI:10.1038/s41598-021-81947-5] [PMID]
[17] J. Norem, Z. Insepov, and A. Hassanein, "An integrated approach to understanding RF vacuum arcs," Scientific Reports, vol. 11, no. 1, p. 2361, 2021. [DOI:10.1038/s41598-021-81947-5] [PMID]
[18] Y. Le Godec and S. Le Floch, "Recent developments of high-pressure spark plasma sintering: an overview of current applications, challenges and future directions," Materials, vol. 16, no. 3, p. 997, 2023. [DOI:10.3390/ma16030997] [PMID]
[18] Y. Le Godec and S. Le Floch, "Recent developments of high-pressure spark plasma sintering: an overview of current applications, challenges and future directions," Materials, vol. 16, no. 3, p. 997, 2023. [DOI:10.3390/ma16030997] [PMID]
[19] H. Lesueur, A. Czernichowski, and J. Chapelle, "Electrically assisted partial oxidation of methane," International journal of hydrogen energy, vol. 19, no. 2, pp. 139-144, 1994. [DOI:10.1016/0360-3199(94)90118-X]
[19] H. Lesueur, A. Czernichowski, and J. Chapelle, "Electrically assisted partial oxidation of methane," International journal of hydrogen energy, vol. 19, no. 2, pp. 139-144, 1994. [DOI:10.1016/0360-3199(94)90118-X]
[20] P. Bruggeman and C. Leys, "Non-thermal plasmas in and in contact with liquids," Journal of Physics D: Applied Physics, vol. 42, no. 5, p. 053001, 2009. [DOI:10.1088/0022-3727/42/5/053001]
[20] P. Bruggeman and C. Leys, "Non-thermal plasmas in and in contact with liquids," Journal of Physics D: Applied Physics, vol. 42, no. 5, p. 053001, 2009. [DOI:10.1088/0022-3727/42/5/053001]
[21] I. E. Agency, World energy outlook. OECD/IEA Paris, 2009.
[21] I. E. Agency, World energy outlook. OECD/IEA Paris, 2009.
[22] C. Guizani, F. E. Sanz, and S. Salvador, "Influence of temperature and particle size on the single and mixed atmosphere gasification of biomass char with H2O and CO2," Fuel Processing Technology, vol. 134, pp. 175-188, 2015. [DOI:10.1016/j.fuproc.2015.01.031]
[22] C. Guizani, F. E. Sanz, and S. Salvador, "Influence of temperature and particle size on the single and mixed atmosphere gasification of biomass char with H2O and CO2," Fuel Processing Technology, vol. 134, pp. 175-188, 2015. [DOI:10.1016/j.fuproc.2015.01.031]
[23] K. Göransson, U. Söderlind, J. He, and W. Zhang, "Review of syngas production via biomass DFBGs," Renewable and Sustainable Energy Reviews, vol. 15, no. 1, pp. 482-492, 2011. [DOI:10.1016/j.rser.2010.09.032]
[23] K. Göransson, U. Söderlind, J. He, and W. Zhang, "Review of syngas production via biomass DFBGs," Renewable and Sustainable Energy Reviews, vol. 15, no. 1, pp. 482-492, 2011. [DOI:10.1016/j.rser.2010.09.032]
[24] G. Council, "GASIFICATION The waste-to-energy solution," ed, 2014.
[24] G. Council, "GASIFICATION The waste-to-energy solution," ed, 2014.
[25] V. Galvita, V. Messerle, and A. Ustimenko, "Hydrogen production by coal plasma gasification for fuel cell technology," International Journal of Hydrogen Energy, vol. 32, no. 16, pp 3899-3906., 2007 [DOI:10.1016/j.ijhydene.2007.05.039]
[25] V. Galvita, V. Messerle, and A. Ustimenko, "Hydrogen production by coal plasma gasification for fuel cell technology," International Journal of Hydrogen Energy, vol. 32, no. 16, pp 3899-3906., 2007 [DOI:10.1016/j.ijhydene.2007.05.039]