ساخت سلول های خورشیدی حساس به رنگ بر پایه ی نانو ذرات دی اکسید تیتانیوم با استفاده از رنگدانه های طبیعی جدید

پیشقدم, مرتضی; فرجامی شایسته, صابر

ساخت سلول های خورشیدی حساس به رنگ بر پایه ی نانو ذرات دی اکسید تیتانیوم با استفاده از رنگدانه های طبیعی جدید

نویسندگان

مرتضی پیشقدم

صابر فرجامی شایسته

دانشگاه گیلان

چکیده

یکی از اجزای اصلی و تعیین کننده سلولهای خورشیدی حساس به رنگ (DSSC_S)، رنگدانه میباشد که از مهمترین ویژگیهای یک رنگدانه خوب جذب بیشتر فوتون ورودی و یا به عبارت دیگر وسیعتر بودن طیف جذبی آن است. با توجه به اینکه فرایند انتقال الکترون در سلول خورشیدی رنگدانهای بر اساس مکانیزمهای فتوالکتروشیمیایی و مدل شبیه سازی آن مثل عمل فتوسنتز در گیاهان است، لذا استفاده از یک رنگدانه طبیعی و مناسب با طیف جذبی بالا میتواند علاوه بر سازگاری با محیط زیست تأثیر بسزایی در افزایش بازدهی سلول داشته باشد. در این پزوهش از عصاره طبیعی میوه گیاهان یاس هلندی، عشقه (پیچک) پنج برگ، کاکتوس اپونتیا، آقطی (پلهم)، ماهونیا، استفاده گردید. نانوذرات دی اکسید تیتانیوم به روش لایه نشانی دکتر بلید بر بستر رسانای شفاف اعمال شد. ساختار بلوری و ویژگی مورفولوژیکی الکترود TiO₂ آماده شده به ترتیب توسط XRD و FESEM مورد بررسی قرار گرفت. همچنین خواص نوری عصارههای رنگ طبیعی با طیف سنجی UV-Vis مورد تجزیه و تحلیل قرار گرفتند. نتایج بدست آمده از مشخصه یابی جریان-ولتاژ نشان میدهند که سلول رنگ آمیزی شده با میوه گیاه یاس هلندی (حلال اتانول) دارای بازدهی بیشتر میباشد. همچنین مقدار چگالی جریان مدار کوتاه، ولتاژ مدار باز، فاکتور پرشدگی و بازدهی برای این سلول به ترتیب mA/cm² 35/12، mV 721، 5/0 و 45/4 بدست آمد. نتایج این پژوهش بیان کننده روشی ساده و قابل انجام با حداقل امکانات برای ساخت سلول های خورشیدی رنگدانهای است.

کلیدواژه‌ها

رنگدانه ی طبیعی

آنتوسیانین

TiO2

سلول خورشیدی حساس به رنگ (DSSC)

فتوولتائیک

عنوان مقاله English

The Fabrication Dye-Sensitized Solar Cell (DSSC) Based on TiO2 Nanoparticles Using New Natural Dyes

نویسندگان English

Morteza Pishghadm

Saber Farjami Shayesteh

University of Guilan

چکیده English

One of the main and determining components of dye-sensitized solar cells (DSSCs) is the pigment, which is one of the most important features of a good pigment to absorb more input photons, or in other words, its wider absorption spectrum. Because the process of electron transfer in a pigmented solar cell is based on photoelectrochemical mechanisms and its simulation model is like photosynthesis in plants, so the use of a natural pigment with a high absorption spectrum can be effective in addition to environmental compatibility. Significantly increase cell efficiency. This study used natural fruit extracts of Dutch jasmine, five-leaf ivy, Cactus Apontia, Acacia, and Mahogany. Titanium dioxide nanoparticles were applied on a transparent conductive substrate by Dr. Blade's coating method. The optical properties of natural dye extracts were investigated by UV-Vis spectroscopy. The crystal structure and morphological properties of TiO₂ electrodes were analyzed by XRD and FESEM, respectively. The results of the current-voltage characterization show that due to the anthocyanin of the Holandi jasmine pigment (with ethanol solvent) and the interaction between the anthocyanin of hydroxyl groups and the TiO₂ surface, this sensor has the best photovoltaic performance and is more efficient among Natural colors are tested. Also, the values of short circuit current density, open-circuit voltage, filling factor, and efficiency for this cell were 12.35 mA / cm2, 721 mV, 0.5, and 4.45, respectively. The results of this study indicate a simple and feasible method with minimal facilities for fabricating dye-sensitized solar cells.

کلیدواژه‌ها English

Natural dyes

Anthocyanin

TiO2

Dye-sensitized solar cell (DSSC)

Photovoltaic

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