logo
Volume 9, Issue 1 (Spring and Summer 2024 2024)                   JMRPh 2024, 9(1): 18-26 | Back to browse issues page

XML Persian Abstract Print


Download citation:
BibTeX | RIS | EndNote | Medlars | ProCite | Reference Manager | RefWorks
Send citation to:

Salmani Shik S. Solvent Effect Investigation on Nonlinear Responses of an Azo-dye: Disperse Red 1. JMRPh 2024; 9 (1) :18-26
URL: http://jmrph.khu.ac.ir/article-1-250-en.html
Kharazmi University
Abstract:   (50 Views)
In this study, the solvent polarity effects on the nonlinear responses of the organic azo dye with the commercial name, Disperse Red 1, were investigated by the z-scan method under 532 nm laser irradiation. The nonlinear optical refraction and absorption were obtained for different solvents. The experimental results reveal that the nonlinear response is highly dependent on the molecular environment around the azo dye and its intermolecular interactions. Since alcohols have a higher order parameter, the nonlinear refraction and absorption decrease with increasing dielectric constant, but for other solvents with low order parameters, the nonlinear indexes increase with increasing dielectric constant. The refractive index is negative and in order of 10-7 cm2/W, which indicates that self-focusing occurs for different solvents.
 
 
Full-Text [PDF 1236 kb]   (24 Downloads)    
Type of Study: Research | Subject: Special
Received: 2025/01/12 | Accepted: 2025/01/21 | Published: 2024/08/31 | ePublished: 2024/08/31

References
1. [1] Sadigh, M. Khadem, M. S. Zakerhamidi, B. Rezaei, and K. Milanchian. "Environment effects on the nonlinear absorption properties of Methylene blue under different power of excitation beam." Journal of Molecular Liquids, 229 548-554, 2017. [DOI:10.1016/j.molliq.2016.12.108]
2. [2] M.S. Zakerhamidi, Sh. Golghasemi Sorkhabi, "Solvent effects on the molecular resonance structures and photo-physical properties of a group of oxazine dyes", J. Lumin. 157, 220-228, 2015. [DOI:10.1016/j.jlumin.2014.08.062]
3. [3] M. Khadem Sadigh, M.S. Zakerhamidi, S.M. Seyed Ahmadian, M. Johari-Ahar, L. Zare Haghighi," Environment effect on spectral and charge distribution characteristics of some drugs of folate derivative"s, Spectrochim. Acta A, 171 10-17, 2017. [DOI:10.1016/j.saa.2016.07.034]
4. [4] A. Jafari, A. Ghanadzadeh, H. Tajalli, M. Yeganeh, M. Moghadam, "Electronic absorption spectra of cresyl violet acetate in anisotropic and isotropic solvents", Spectrochim. Acta A Mol. Biomol. Spectrosc. 66, 717-725, 2007. [DOI:10.1016/j.saa.2006.04.016]
5. [5] M. Khadem Sadigh, M.S. Zakerhamidi, "Media polarity and concentration roles on the third order nonlinear behaviors of thiazine dyes", Opt. Laser Technol. 100 216-224, 2018. [DOI:10.1016/j.optlastec.2017.10.007]
6. [6] S. Salmani, E. Safari, M.H. Majles Ara, M.S. Zakerhamidi, "Optimizing experimental parameters on OPC in PMMA polymer doped azo dye", Journal of Molecular Liquids, Volume 182,102-105, 2013. [DOI:10.1016/j.molliq.2013.03.010]
7. [7] M.J. Moran, C.Y. She, R.L. Carman, "Interferometric measurements of nonlinear
8. refractive-index coefficient relative to CS2 in laser-system-related materials", IEEE J. Quantum Electron. 11, 259-263, 1975. [DOI:10.1109/JQE.1975.1068611]
9. [8] M. Sheik-Bahae, A.A. Said, T.H. Wei, D.J. Hagan, V. Stryland, "Sensitive measurement of optical nonlinearities using a single beam", IEEE J. Quantum Electron. 26, 760-769, 1990. [DOI:10.1109/3.53394]
10. [9] MHM Ara, SH Mousavi, E Koushki, S Salmani, "Nonlinear optical responses of Sudan IV doped liquid crystal by z-scan and moiré deflectometry techniques", Journal of Molecular Liquids, 142, 29-31, 2008. [DOI:10.1016/j.molliq.2008.04.011]
11. [10] M. Wielgus, M. Samoć, W. Bartkowiak, "Two-photon absorption of Crystal Violet in solutions: analysis of the solvent effect and aggregation process based on linear and nonlinear absorption spectra", Journal of Molecular Liquids, 222, 125-132, 2016. [DOI:10.1016/j.molliq.2016.07.022]
12. [11] R.K. Rekha, A. Ramalingam, Nonlinear characterization and optical limits effects on Carmin dyes, Indian J. Sci Technol. 2, 27-31, 2009. [DOI:10.17485/ijst/2009/v2i8.2]
13. [12] A. Owyoung, "Ellipse rotations studies in laser host materials", IEEE J. Quantum Electron. 9, 1064-1069, 1973. [DOI:10.1109/JQE.1973.1077417]
14. [13] Al-Hamdani U.J.; A. Hassan Q.M.; Elias R.S.; Sultan H.A.; Alshlshat S.A.; Emshary C.A., "Thermal nonlinearity and all-optical switching of synthesized Azo-Cl compound", Optical Materials, 139, 113824, 2023. [DOI:10.1016/j.optmat.2023.113824]
15. [14] S Salmani, H Asgari, "the Matrix Effect on Nonlinear Optical Responses of Disperse Orange 25: Optical Bistability and Z-Scan", Journal of Fluorescence, 32 (6), 2281-2286, 2022. [DOI:10.1007/s10895-022-03025-x]
16. [15] Mohamed Yahya, Nurgül Seferoğlu, Gökhan Kaplan, Yahya Nural, Alberto Barsella, Zeynel Seferoğlu, "Synthesis, nonlinear optical properties, photophysical, and theoretical studies of azo dye bearing coumarin-thiophene", Journal of Molecular Structure, 1273, 134257,2023. [DOI:10.1016/j.molstruc.2022.134257]
17. [16] Puja O. Gupta, Nagaiyan Sekar, "Investigation of heterocyclic azo dyes for dye-sensitized solar cells and non-linear optical properties: Synthesis and in-silico studies", Journal of Molecular Structure, Volume 1321, Part 4,140035, 2025. [DOI:10.1016/j.molstruc.2024.140035]
18. [17] S. Salmani, M.H. Majles Ara, "The optical length effect, diffraction pattern and thermal lensing of Disperse Orange 25", Optics and Laser Technology, 82, 34-37, 2016. [DOI:10.1016/j.optlastec.2016.02.016]
19. [18] Brzozowski L.; Sargent E.H., "Azobenzenes for photonic network applications: Third-order nonlinear optical properties ", Journal of Materials Science: Materials in Electronics, Volume 12, Issue 9, Pages 483 - 489, 2001. [DOI:10.1023/A:1012446007088]
20. [19] M. Sheik-Bahae, A.A. Said, V. Stryland, High-sensitivity, "single-beam n2 measurements", Optics Letter. 14, 955-957, 1989. [DOI:10.1364/OL.14.000955]
21. [20] E. Koushki, A. Farzaneh, S.H. Mousavi., "Closed aperture z-scan technique using the Fresnel-Kirchhoff diffraction theory for materials with high nonlinear refractions.", Applied Physics B, Vol. 99, 565-570, 2010. [DOI:10.1007/s00340-010-3913-1]
22. [21] Morteza A Sharif, Somayeh Salmani, Salman Mohajer, MH Majles Ara, "Experimental comparison of nonlinear optical properties between graphene oxide and reduced graphene oxide", Journal of Electronic Materials, 48, 6414-6420, 2019. [DOI:10.1007/s11664-019-07442-w]
23. [22] C. Reichardt, Solvents and Solvent Effects in Organic Chemistry, 2nd ed., VCH, New York, 1988.

Add your comments about this article : Your username or Email:
CAPTCHA

Send email to the article author


Rights and permissions
Creative Commons License This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.