بررسی اثر تابش پلاسمایی نانوساختارهای کربن شبه الماس بر عملکرد جداسازی غشاهایی بر پایه PES، PP و PVDF

کیامهر, زینب; شفیعی, مجتبی; شگری, بابک; رضوی راد, سیدعلی

نشریه پژوهش های نوین فیزیک

EN FA

دوره 10، شماره 1 - ( بهار و تابستان 1404 ) جلد 10 شماره 1 صفحات 13-1 | برگشت به فهرست نسخه ها

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RefWorks

Kiamehr Z, Shafiee M, Shokri B, Razavi Rad S A. Investigating the effect of plasma irradiation of diamond-like carbon nanostructures on the separation performance of membranes based on PES, PP and PVDF. JMRPh 2025; 10 (1) :1-13
URL: http://jmrph.khu.ac.ir/article-1-256-fa.html

کیامهر زینب، شفیعی مجتبی، شگری بابک، رضوی راد سیدعلی. بررسی اثر تابش پلاسمایی نانوساختارهای کربن شبه الماس بر عملکرد جداسازی غشاهایی بر پایه PES، PP و PVDF. نشریه پژوهش های نوین فیزیک. 1404; 10 (1) :1-13

URL: http://jmrph.khu.ac.ir/article-1-256-fa.html

بررسی اثر تابش پلاسمایی نانوساختارهای کربن شبه الماس بر عملکرد جداسازی غشاهایی بر پایه PES، PP و PVDF

زینب کیامهر^*

، مجتبی شفیعی

، بابک شگری

، سیدعلی رضوی راد

دانشگاه تفرش

چکیده: (182 مشاهده)

چالش رو به رشد رسوب غشایی در فرآیندهای تصفیه آب، به ویژه در کارخانه های نمک زدایی، نیازمند رویکردهای نوآورانه برای افزایش عملکرد غشا است. این مطالعه یک استراتژی جدید اصلاح سطح را برای غشاهای متفاوت (PES, PVDF, PP) با استفاده از نانوساختارهای کربن شبه الماس از طریق رسوب دهی بخار شیمیایی افزایش‌یافته با پلاسما ارائه می‌کند. اهداف اولیه بهبود آبدوستی غشا، افزایش خواص ضدرسوب و افزایش راندمان دفع نمک با حفظ یکپارچگی ساختاری بود. یک بررسی سیستماتیک برای مقایسه اصلاحات پوشش نانوساختارهای کربن شبه الماس تحت شرایط بهینه پلاسما (قدرت 40 وات، فشار 70 میلی‌تور، تابشدهی 30 دقیقه‌ای) انجام شد. مشخصه‌های سطحی هر سه غشای مورد مطالعه، ترکیب موفقیت‌آمیز نانوساختارهای کربن شبه الماس را نشان داد، که توسط طیف‌سنجی FTIR تأیید شد و تجزیه و تحلیل رامان که پوشش کربنی یکنواخت را بدون تشکیل ساختار کریستالی نشان می‌دهد. غشاهای اصلاح شده بهبود قابل توجهی در خواص سطحی نشان دادند، که نشان دهنده افزایش آبدوستی است. تجزیه و تحلیل AFM صاف شدن سطح قابل توجهی را نشان داد، که به بهبود خواص ضد رسوب کمک می کند. ارزیابی عملکرد پیشرفت‌های استثنایی را در پارامترهای کلیدی غشاهای PES, PVDF نشان داد: شار آب خالص افزایش یافت، در حالی که دفع نمک تا 99٪ بهبود یافت. غشاهای اصلاح‌شده به نرخ بازیابی شار بالایی در مقایسه با غشای اصلاح ‌نشده دست یافت که نشان‌دهنده خواص ضد رسوب برتر است. تست های پایداری در محلول های نمک اشباع، خواص تمیز کنندگی آسان و حفظ آبدوستی را پس از چندین دوره شستشو نشان داد که نشان دهنده دوام عالی است. این کار یک رویکرد اقتصادی مقرون به صرفه را برای توسعه غشاهای ضد رسوب با کارایی بالا با کاربردهای بالقوه در کارخانه‌های نمک‌زدایی و تأسیسات تصفیه فاضلاب معرفی می‌کند. یافته‌ها بینش‌های ارزشمندی را در مورد رابطه بین اصلاح سطح، ویژگی‌های ساختاری و عملکرد غشاء ارائه می‌دهند و به پیشرفت فناوری‌های تصفیه آب پایدار کمک می‌کنند.

واژه‌های کلیدی: اصلاح سطح، اصلاح پلاسمایی، غشاء با تراوایی بالا، نانوساختارهای کربن شبه الماس، ضد رسوب، نمک زدایی.

متن کامل [PDF 1045 kb] (55 دریافت)

نوع مطالعه: پژوهشي | موضوع مقاله: تخصصي
دریافت: 1403/12/8 | پذیرش: 1404/5/14 | انتشار: 1404/6/31 | انتشار الکترونیک: 1404/6/31

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