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Kiamehr Z, Shafiee M, Shokri B, Razavi Rad S A. Investigating the effect of plasma irradiation of diamond-like carbon nanostructures on the separation performance of membranes based on PES, PP and PVDF. JMRPh 2025; 10 (1) :1-13
URL: http://jmrph.khu.ac.ir/article-1-256-en.html
Tafresh University
Abstract:   (105 Views)
The growing challenge of membrane fouling in water treatment processes, especially in desalination plants, requires innovative approaches to enhance membrane performance. This study presents a novel surface modification strategy for different membranes (PES, PVDF, PP) using diamond-like carbon nanostructures via plasma-enhanced chemical vapor deposition. The primary objectives were to improve membrane hydrophilicity, enhance antifouling properties, and increase salt rejection efficiency while maintaining structural integrity. A systematic review compared diamond-like carbon nanostructure coating modifications under optimized plasma conditions (40 W power, 70 mTorr pressure, 30 min irradiation). The surface characterization of all three studied membranes demonstrated the successful incorporation of diamond-like carbon nanostructures, as confirmed by FTIR spectroscopy and Raman analysis, which revealed a uniform carbon coating without forming a crystalline structure. The modified membranes showed significant improvement in surface properties, indicating increased hydrophilicity. AFM analysis revealed significant surface smoothing, which contributes to improved antifouling properties. Performance evaluation revealed exceptional improvements in key parameters of PES, and PVDF membranes: pure water flux increased, while salt rejection improved by up to 99%. The modified membranes achieved high flux recovery rates compared to the unmodified membrane, indicating superior antifouling properties. Stability tests in saturated salt solutions revealed easy cleaning properties and hydrophilicity retention after multiple wash cycles, indicating excellent durability. This work introduces a cost-effective approach to developing high-performance antifouling membranes with potential applications in desalination plants and wastewater treatment facilities. The findings provide valuable insights into the relationship between surface modification, structural properties, and membrane performance, and contribute to the advancement of sustainable water treatment technologies.
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Type of Study: Research | Subject: Special
Received: 2025/02/26 | Accepted: 2025/08/5 | Published: 2025/09/22 | ePublished: 2025/09/22

References
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52. ]52[ ز کیامهر، ب فرخی، م حسینی، 1400، تاثیر پلاسما بر خواص شیمی-فیزیکی غشاء نانوفیلتراسیون مورد استفاده در دستگاههای تصفیه آب دریا، دانشگاه اراک، pp. 1-130.
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54. [2] B. Farokhi, M. Rezaei, Z. Kiamehr and S. Hosseini, "A new approach to provide high water permeable polyethersulfone based nanofiltration membrane by air plasma treatment", International Journal of Engineering, vol. 32, no. 354, 2019.
55. [3] Z. Kiamehr, B. Farokhi, S. Hosseini, "Development of a highly-permeable thin-film-based nanofiltration membrane by using surface treatment with Air-Ar plasma", Korean Journal of Chemical Engineering, vol. 38, no. 114, 2021.
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57. [5] S. Arefi, A. Khataee, M. Safarpourd, V. Vatanpour, "Modification of Polyethersulfone Ultrafiltration Membrane Using Ultrasonicassisted Functionalized MoS2 for Treatment of Oil Refinery Wastewater", Separation and Purification Technology, vol. 238, no. 6495, 2020.
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59. [7] Z. Kiamehr, "Modification of a highly-permeable thin-film-based nanofiltration membrane (PVC) to increase efficiency and separation by Air Plasma Treatment", IEEE Trans. Plasma Sci. vol. 50, no. 2952, 2022.
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61. [9] I. Soroko, Y. Bhole, A. Livingston, "Environmentally Friendly Route for the Preparation of Solvent Resistant Polyimide Nanofiltration Membranes", Green Chemistry, vol. 13, no. 162, 2011.
62. [10] Y. Zhao, X. Zhu, K. Wee, R. Bai, "Achieving Highly Effective Non-Biofouling Performance for Polypropylene Membranes Modified by Uv-Induced Surface Graft Polymerization of Two Oppositely Charged Monomers", The Journal of Physical Chemistry B, vol. 114, no. 2422, 2010.
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66. [14] Y. Koc, A. Mello, G. McHale, M. Newton, P. Roach, N. Shirtcliffe, "Nano-scale Superhydrophobicity: Suppression of Protein Adsorption and Promotion of Flow-induced Detachment", Lab on a Chip, vol. 8, no. 528, 2008.
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68. [16] Q. Wang, Z. Wang, J. Wang, Z. Wu, "Antifouling behaviours of PVDF/nano-TiO2 composite membranes revealed by surface energetics and quartz crystal microbalace monitoring," RSC Adv, vol. 4, pp. 43990, 2014.
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71. [19] M. Padaki, A. Isloor, R. Kumar, A. Ismail, T. Matsuura, "Characterization and Desalination Study of Composite Nf Membranes", Journal of Membrane Science, vol. 428, no. 489, 2013.
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75. [23] J. Garcia, M. Iborra, M. Alcaina, J. Mendoza L. Pastor, "Development of Fouling-Resistant Polyethersulfone Ultrafiltration Membranes via Surface UV Photografting with Polyethylene Glycol/Aluminum Oxide Nanoparticles", Separation and Purification Technology, vol. 135, pp. 88, 2014.
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84. [32] V. Vatanpour, S. Madaeni, L. Rajabi, S. Zinadini, A. Derakhshan, "Boehmite Nanoparticles as a New Nanofiller for Preparation of Antifouling Mixed Matrix Membranes", Journal of Membrane Science, vol. 401, pp. 132, 2012.
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90. [38] P. Qu, H. Tang, Y. Gao, L. Zhang, S. Wang, "Polyethersulfone Composite Membrane Blended with Cellulose Fibrils", BioResources, vol. 5, pp. 2323, 2010.
91. [39] D. Pavia, G. Lampman, G. Kriz, G. Randall, "Introduction to Organic Laboratory Techniques: A Small-Scale Approach: Cengage Learning", Second ed., Brooks/Cole: Belmont, CA, 2005.
92. [40] L. Ge, Z. Zhu, V. Rudolph, "Enhanced Gas Per- meability by Fabricating Functionalized Multi-Walled Carbon Nanotubes and Polyethersulfone Nanocomposite Membrane", Separation and Purification Technology, vol. 78, no. 76, 2011.
93. [41] B. Li, W. Zhao, Y. Su, Z. Jiang, X. Dong, W. Liu, "Enhanced Desulfurization Performance and Swelling Re- sistance of Asymmetric Hydrophilic Pervaporation Mem- brane Prepared Through Surface Segregation Technique", Journal of Membrane Science, vol. 326, pp. 556, 2009.
94. [42] J. Jhaveri, C. Patel, Z. Murthy, "Preparation, characterization and application of GO-TiO2 /PVC mixed matrix membranes for improvement in performance", Journal of Industrial and Engineering Chemistry, vol. 52, no. 138, 2017.
95. [43] F. Wu, R. Tseng, R. Juang, "A review and experimental verification of using chitosan and its deriva-tives as adsorbents for selected heavy metals", Journal of Environmental Management, vol. 91, pp. 798, 2010.
96. [44] V. Vatanpour, S. Madaeni, R. Moradian, S. Zinadini, B. Astinchap, "Novel anti befouling nanofiltration polyethersulfone membrane fabricated from embedding TiO2 coated multiwalled carbon nanotubes", Separation and Purification Technology, vol. 90, no. 69, 2012.
97. [45] R. Damodar, S. You, H. Chou, "Study the self-cleaning, antibacterial and photocatalytic properties of TiO2 entrapped PVDF membranes", Journal of Hazardous Materials, vol. 172, pp. 1321, 2009.
98. [46] M. Li, Z. Zeng, Y. Zhao, C. Hong, Q. Li, "Development of an antimicrobial and antifouling PES membrane with ZnO/Poly(hexamethylene biguanide) nanocomposites incorporation", Chemical Engineering Journal, vol. 481, pp. 148744, 2024.
99. [47] C. Liu, M. Zhang, F. Gao, P. Hong, Z. Wang, "Ta-Fe in-situ coating PES membrane and its application in oily wastewater treatment: insight into modification and anti-fouling mechanisms", Separation and Purification Technology, vol. 346, pp. 127506, 2024.
100. [48] R. Desiriani, L. Marbelia, A. Kurniawan, I.G. Wenten, "Preparation of polyethersulfone ultrafiltration membrane coated natural additives toward antifouling and antimicrobial agents for surface water filtration", Journal of Environmental Chemical Engineering, vol. 12, pp. 111797, 2024.
101. [49] M. Zhai, Y. Li, J. Wang, F. Liu, "High-performance loose nanofiltration membranes with excellent antifouling properties for dye/salt separation", Journal of Membrane Science, vol. 708, pp. 123028, 2024.
102. [50] F. Pasandidehpour, S.R. Ghaffarian, T. Mohammadi, "A Review of the Performance of Nanofiltration Membranes Modified with Inorganic, Carbon Nanomaterials and their Combinations", Journal of Water and Wastewater Science and Engineering, vol. 8, pp. 15, 2023.
103. [51] M.E. Batouti, O.M. Ahmed, R. El-Ghazaly, "Review of New Approaches for Fouling Mitigation in Membrane Separation Processes in Water Treatment Applications", Separations, vol. 9, no. 1, 2022.
104. ]52[ ز کیامهر، ب فرخی، م حسینی، 1400، تاثیر پلاسما بر خواص شیمی-فیزیکی غشاء نانوفیلتراسیون مورد استفاده در دستگاههای تصفیه آب دریا، دانشگاه اراک، pp. 1-130.

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